Chemistry questions and solutions
Browse original practice and official past-paper questions. Each question has its own link, with its source and worked solution.
364 questions · Page 8 of 16
- Q25 · 2021 QCAA · Paper 1 · 5 marksChemical equilibriumQUESTION 25 (5 marks) 2+(aq), An equilibrium is formed between two differently coloured cobalt species, Co(H2O)6 2‒(aq), which is blue. The equation for this equilibrium is shown. which is pink, and CoCl4 2+(aq) + 4Cl–(aq) ⇌ CoCl4 2–(aq) + 6H2O(l) Co(H2O)6 a) Apply Le Châtelier’s principle to predict the visible effect of adding AgNO3 to an 2+ and CoCl4…
- Q26 · 2021 QCAA · Paper 1 · 5 marksChemical equilibriumQUESTION 26 (5 marks) The graph represents changes in concentration over time for three gaseous molecules (X2, Y2 and XY) in a closed system at constant temperature and pressure. X2 + Y2 ⇌ 2XY 4 3 XY Concentration (mol L–1) X2 2 Y2 1 0 Time a) Identify whether XY is the reactant or the product. [1 mark] b) Calculate the equilibrium constant (Kc) value.…
- Q27 · 2021 QCAA · Paper 1 · 6 marksRedox and electrochemistryQUESTION 27 (6 marks) Arsenous acid, H3AsO3, reacts with nitrate ions to form arsenic acid, H3AsO4, and nitrogen dioxide. a) Determine the oxidation number of arsenic in arsenous acid. [1 mark] b) Use half-equations to balance the reaction. [4 marks] c) Determine which species is reduced in this reaction. [1 mark]
- Q28 · 2021 QCAA · Paper 1 · 3 marksAcids, bases and titrationQUESTION 28 (3 marks) Sketch the titration curve formed when 20 mL of 0.1 M butylamine (pKa = 10.0) is titrated with 0.1 M hydrochloric acid. 14 13 12 11 10 9 8 7 pH 6 5 4 3 2 1 0 0 2 4 6 8 10 12 14 16 18 20 22 24 26 28 Volume (mL) Note: If you make a mistake in the sketch, cancel it by ruling a single diagonal line through your work
- Q1 · 2021 QCAA · Paper 2 · 11 marksAcids, bases and titrationQUESTION 1 (11 marks) Phosphoric acid (H3PO4) is a common triprotic acid that dissociates fully in three stages. The dissociation equations are shown in the table. Ka Stage Dissociation equation 7.1 × 10–3 1 H3PO4(aq) + H2O(l) ⇌ H2PO4 –(aq) + H3O+(aq) 2–(aq) + H3O+(aq) 6.5 × 10–8 2 H2PO4 –(aq) + H2O(l) ⇌ HPO4 2–(aq) + H2O(l) ⇌ PO4 3–(aq) + H3O+(aq…
- Q2 · 2021 QCAA · Paper 2 · 10 marksPolymers and biomoleculesQUESTION 2 (10 marks) Polypropene (PP) is a polymer formed from propene. Polyethylene terephthalate (PET) is a polymer formed from monomers of carboxylic acid and alcohol. A section of the PET polymer is shown. O O C C O O CH2 CH2 n a) Draw the structural formulas of the monomers used to form PET. [2 marks] i) Carboxylic acid monomer ii) Alcohol monomer N…
- Q3 · 2021 QCAA · Paper 2 · 11 marksOrganic chemistryQUESTION 3 (11 marks) Four colourless liquids, A, B, C and D, are known to be butane, 1-butene, 2-butanol and 1-propanol. Reactions are carried out to identify the liquids. The results are shown. Test 1 A B C D Bromine (Br2) water No reaction No reaction No reaction Decolourised Test 2 A B C Excess acidified potassium Decolourised, Decolourised, No reaction…
- Q4 · 2021 QCAA · Paper 2 · 9 marksChemical equilibriumQUESTION 4 (9 marks) 5.00 × 10–4 moles of hydrogen gas is mixed with 1.00 × 10–3 moles of iodine vapour in a sealed 1.00 L vessel at 455.0 °C. The concentration of hydrogen iodide gas formed at equilibrium is 9.30 × 10–4 M. The balanced equation for the reaction is shown. H2(g) + I2(g) ⇌ 2HI(g) a) Write the equilibrium law expression for the reaction. [1…
- Q5 · 2021 QCAA · Paper 2 · 10 marksRedox and electrochemistryQUESTION 5 (10 marks) A sample of iron ore was tested for its iron content using the experimental procedure outlined. 8.00 g of iron Reacted with Titrated with Fe2+(aq) Fe3+(aq) ore sample H2SO4(aq) KMnO4(aq) All the iron (Fe) in the sample was converted to Fe2+(aq) by reacting it with H2SO4(aq), forming hydrogen gas. The solution made up to a final volume…
- Q1 · 2020 QCAA · Paper 1 · 1 markChemical equilibriumQUESTION 1 A partly filled water bottle is sealed and left on a bench in a room with a constant temperature. After several minutes, it is noted that the water level in the bottle remains constant. In the water bottle, the rate of evaporation is (A) less than the rate of condensation. (B) greater than the rate of condensation. (C) equal to the rate of condens…
- Q2 · 2020 QCAA · Paper 1 · 1 markRedox and electrochemistryQUESTION 2 Mg(s) + 2Ag (aq) > 2Ag(s) + Mg”*(aq) Determine which of the following statements is true for the chemical reaction. (A) Silver ions are reduced and act as a reducing agent. (B) Silver ions are oxidised and act as a reducing agent. (C) Magnesium atoms are reduced and act as a reducing agent. (D) Magnesium atoms are oxidised and act as a reducing ag…
- Q3 · 2020 QCAA · Paper 1 · 1 markOrganic chemistryQUESTION 3 D4 N—O—* This general chemical equation represents the following type of reaction. (A) addition (B) hydrolysis (C) esterification (D) condensation
- Q4 · 2020 QCAA · Paper 1 · 1 markOrganic chemistryQUESTION 4 Oil of wintergreen is a chemical compound with the following chemical structure. O OH Identify the functional groups present in oil of wintergreen. (A) alcohol and ester (B) alcohol and ketone (C) alcohol and aldehyde (D) alcohol and carboxylic acid
- Q5 · 2020 QCAA · Paper 1 · 1 markChemical equilibriumQUESTION 5 The equilibrium constants of four different reactions are given. In which reaction does the equilibrium lie furthest to the left? Reaction Ke (A) | PC1,(g) + Cl,(g) = PCI,(g) 2.4 x 10! (B) | AgiO,(s) = Agt(aq) + 103 (aq) 5 1 14 1 3 9 1090 585 38 23 96.034164 3.0 5 1 14 1 3 10 1142 591 12 13 94.427597 x 5 1 14 1 3 11 1170 578 54 29 28.200943 1078 4…
- Q6 · 2020 QCAA · Paper 1 · 1 markRedox and electrochemistryQUESTION 6 Calculate the cell potential produced by a Zn(s) | Zn**(aq) || Cu**(aq) | Cu(s) galvanic cell under standard conditions. (A) -L10V (B) -0.42V (C) +0.34V (D) +110V
- Q7 · 2020 QCAA · Paper 1 · 1 markAcids, bases and titrationQUESTION 7 Acid Concentration (M) pH HPO, 2.0 x 107 19 HCN 1.5 x 107 5.0 H,SO, 9.0 x 10° 1.0 CH;COOH 1.0 x 107 2.8 Analyse the experimental data to determine the relative strength of the acids from strongest to weakest. (A) H,SO, > H;PO, > HCN > CH,;,COOH (B) H,SO,> HPO, > CH,COOH > HCN (C) HCN >CH;COOH > H2SO, > H3PO, (D) HCN > CH;COOH > H;PO, > H,SO,
- Q8 · 2020 QCAA · Paper 1 · 1 markOrganic chemistryQUESTION 8 An organic compound, X, reacts with sodium hydrogen carbonate to form carbon dioxide gas. Compound X is (A) an amine. (B) ahaloalkane. (C) acarboxylic acid. (D) aprimary alcohol.
- Q9 · 2020 QCAA · Paper 1 · 1 markChemical equilibriumQUESTION 9 Phosgene gas (COCI,) is formed by the following reaction. CO(g) + Cl(g) = COCL(g) AH =-110 kJ mol! Which of the following statements is true for the system at equilibrium? (A) Removing Cl,(g) will increase the yield of phosgene and keep the K, value constant. (B) Adding a catalyst will increase the yield of phosgene and keep the K, value constant.…
- Q10 · 2020 QCAA · Paper 1 · 1 markRedox and electrochemistryQUESTION 10 Voltage source -— Fork (cathode) Which of the following is true for the electrochemical cell? Reaction Anode Flow of electrons (A) | spontaneous oxidation From the negative terminal of the power pack, through the wire to the negative electrode. (B) | spontaneous positive electrode From the positive terminal of the power pack, through the wire and…
- Q11 · 2020 QCAA · Paper 1 · 1 markAcids, bases and titrationQUESTION 11 Determine the colour of a solution with a pH of 9.6 containing bromocresol green indicator. (A) pink (B) blue (C) green (D) yellow
- Q12 · 2020 QCAA · Paper 1 · 1 markOrganic chemistryQUESTION 12 HN _ _/CH,— CH, H~ NH Apply IUPAC rules to name the molecule. (A) cis—2—pentene (B) trans—2—pentene (C) cis—l—ethyl-2—methylethene (D) trans—\-ethyl—2—methylethene
- Q13 · 2020 QCAA · Paper 1 · 1 markAcids, bases and titrationQUESTION 13 14.00 12.00 10.00 pH of solution 8.00 IV 6.00 4.00 Il 2.00 II 0.00 0.00 0.50 1.00 1.50 2.00 Volume of NaOH added (mL) Identify the equivalence point on the titration curve. (A) I (B) I (C) Il (D) IV
- Q14 · 2020 QCAA · Paper 1 · 1 markChemical equilibriumQUESTION 14 Ammonia gas reacts with oxygen gas in the following equilibrium reaction. 4NH(g) + 30(g) = 2N2(g) + 6H20(g) The equilibrium expression for the reaction is so (NHEIOS () TNgIEO] a DNallthol (®) INEJIOJ NH3}‘[03) © INPTH.0F NoP{HZO}° ©) INE OF
- Q15 · 2020 QCAA · Paper 1 · 1 markOrganic chemistryQUESTION 15 HH AH HA WR WH WA A WW A AW A OR Gg a a 7 H—C—C—C—C— C—C—C—C—C=C— C—C—C—C—C—C—C—C If | | to tt df | | | | t | L ‘ow H H H H HHH 4H H H H HH HUH This compound is an unsaturated fatty acid because it contains a (A) double bond and a carboxylic acid group. (B) long carbon chain and a carboxylic acid group. (C) double bond, an aldehyde group and a hy…