Q92 · Practice questionComplex unfamiliar6 marks
QUESTION 92 (6 marks)
Ethanoic acid reacts with ethanol in a non-aqueous homogeneous mixture of constant volume 100.0 mL. Initially each reactant has concentration 0.100 mol L⁻¹ and neither product is present. For this model, . The ester molar mass is 88.1 g mol⁻¹.
a) Calculate the equilibrium ester concentration. [3 marks]
b) Calculate the equilibrium ester mass and its percentage of the stoichiometric maximum yield. [2 marks]
c) Explain the effect of removing water as it forms. [1 marks]
WORKED SOLUTION
6 marksPractice marking scheme
Equilibrium ester concentration 0.0667 mol L⁻¹; mass 0.587 g; yield 66.7%; water removal promotes further ester formation.
Let ester and water be x, and both reactants 0.100−x. , so and . Mass= g. The maximum is 0.0100 mol, giving 66.7%. Removing a product shifts equilibrium forward.
- Constructs correct concentration changes. [1 marks]
- Sets 4 = x²/(0.100−x)². [1 marks]
- Solves x = 0.0667 mol L⁻¹. [1 marks]
- Calculates ester mass 0.587 g. [1 marks]
- Calculates yield 66.7%. [1 marks]
- Explains water removal shifts equilibrium towards ester. [1 marks]
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