Q86 · Practice questionComplex unfamiliar7 marks
QUESTION 86 (7 marks)
A saturated solution of is filtered to remove all undissolved solid. At , and . Assume dissolution is the only significant source of hydroxide.
a) Calculate the molar solubility. [2 marks]
b) Calculate the pH. [2 marks]
c) Calculate the volume of 0.00500 mol L⁻¹ HCl needed to neutralise all hydroxide in 20.0 mL of the filtered solution. [3 marks]
WORKED SOLUTION
7 marksPractice marking scheme
; pH = 10.52; HCl = 1.32 mL.
, so . , pOH=3.4812, pH=10.5188. Hydroxide moles ; L. Filtering prevents additional solid from dissolving during titration.
- Sets Ksp = 4s³. [1 marks]
- Calculates correct s. [1 marks]
- Calculates [OH⁻] = 2s and pOH. [1 marks]
- Calculates pH = 10.52. [1 marks]
- Calculates hydroxide moles in 20.0 mL. [1 marks]
- Uses 1:1 neutralisation with HCl. [1 marks]
- Calculates acid volume 1.32 mL. [1 marks]
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