Q74 · Practice questionSimple familiar4 marks
QUESTION 74 (4 marks)
Two polypropene samples have identical chain lengths. In X, methyl groups follow a regular isotactic arrangement. In Y, they follow an irregular atactic arrangement.
a) Explain which sample is likely to pack more regularly and be more crystalline. [2 marks]
b) Predict which sample generally has greater stiffness, with a reason. [2 marks]
WORKED SOLUTION
4 marksPractice marking scheme
X is more crystalline and generally stiffer because its regular arrangement supports ordered close packing and stronger collective interchain attractions.
A repeating stereochemical arrangement facilitates alignment of neighbouring chains. The disordered placement in atactic material frustrates ordered packing. Ordered regions restrict chain movement.
- Selects X as more crystalline. [1 marks]
- Explains regular stereochemistry permits ordered packing. [1 marks]
- Predicts X is generally stiffer. [1 marks]
- Links closer packing/interchain attractions to restricted motion. [1 marks]
Practice question aligned to the current QCAA syllabus; review the worked solution and marking criteria.
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