Q52 · Practice questionComplex familiar4 marks
QUESTION 52 (4 marks)
The following standard reduction potentials are provided: , , .
a) Rank the metal ions from strongest to weakest oxidising agent. [1 marks]
b) Determine whether zinc metal can spontaneously reduce magnesium ions under standard conditions. Justify with a calculated cell potential. [2 marks]
c) Explain why a non-standard measured cell potential need not equal a value calculated from these data. [1 marks]
WORKED SOLUTION
4 marksPractice marking scheme
a) Cu²⁺ > Zn²⁺ > Mg²⁺. b) No, −1.61 V. c) Conditions may differ from standard concentration or temperature.
Greater reduction potential means stronger electron acceptance. For Mg²⁺ reduction coupled to Zn oxidation, V, so the reaction as proposed is non-spontaneous.
- Ranks Cu²⁺, Zn²⁺, Mg²⁺ correctly. [1 marks]
- Calculates −1.61 V. [1 marks]
- Uses negative E° to reject spontaneity. [1 marks]
- Names a relevant non-standard condition. [1 marks]
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