QUESTION 8 (2 marks)
In the aqueous solution of a chromate salt, an equilibrium exists between the yellow chromate ions and the orange dichromate
ions. This equilibrium can be represented by the
equation shown.
Explain, at an atomic level, why no colour change occurs once the chromate–dichromate solution has established equilibrium.
QCAA guide · typeset solution
QCAA sample response and mark allocation
8 | At equilibrium, the forward reaction rate equals the reverse reaction rate. Therefore, yellow chromate ions and orange dichromate ions are re-formed at the same rate at which they are broken down, so the colour remains constant because the [CrO42–] and [Cr2O72–] remain constant. | • identifies that the forward reaction rate equals the reverse reaction rate at equilibrium [1 mark] • explains that the colour remains constant because the [CrO42–] and [Cr2O72–] remain constant [1 mark] |
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