QUESTION 2 (6 marks)
Phenol red (HIn) is a weak acid that acts as an indicator as shown.
a) Identify the conjugate base of phenol red.
[1 mark]
b) Determine the dissociation constant (Ka) of phenol red.
[1 mark]
c) Explain the relationship between the pH range of colour change for phenol red and its pKa value.
[4 marks]
QCAA guide · typeset solution
QCAA sample response and mark allocation
2a) | Conjugate base is In–. | • identifies conjugate base is In–[1 mark] |
2b) | apa10KK−=7.98a101.26 10K−−==× | 8 − is 1. 6 2 10 K × [1 mark] • determines a |
2c) | Phenol red changes colour when the concentration of the yellow weak acid form (HIn) equals the concentration of the red conjugate base form (In–). When [HIn] = [In–], the Ka of phenol red equals [H+] and pH equals the pKa (7.9). However, the colour change of phenol red occurs over a pH range equal to pKa ±1, because visible colour change can be observed when the [HIn] : [In–] changes by a ratio of 1:10. | • identifies that colour change occurs when the [HIn] = [In–] [1 mark] • explains that when [HIn] = [In–], the Ka of phenol red equals [H+], and therefore pH equals the pKa [1 mark] • identifies that the pH range of colour change is pKa ±1 [1 mark] • explains that the pH range of colour change occurs either side of pKa because colour change is detected when the [HIn] : [In–] changes [1 mark] |
QCAA sample response and marking criteria reproduced from the official guide.
Compare your working with the guide above.