QUESTION 23 (5 marks)
An aqueous solution of sodium hydroxide (NaOH) was titrated against a 30.0 mL aliquot of a 0.012 M potassium hydrogen phthalate (KHP) standard aqueous solution. The balanced chemical equation for the reaction is shown.
The results are shown in the titration curve.
a) Determine whether KHP is a strong or weak acid. Identify one feature from the titration curve to support your reasoning.
[2 marks]
b) Explain why KHP(aq) is used as the standard solution rather than NaOH(aq).
[1 mark]
c) Calculate the concentration of NaOH(aq). Show your working.
[2 marks]
QCAA guide · typeset solution
QCAA sample response and mark allocation
23a) | KHP is a weak acid. The titration curve contains a buffer region. | • determines KHP is a weak acid [1 mark] • identifies the buffer region [1 mark] |
23b) | KHP does not absorb water from the air; therefore, an accurate concentration can be determined for KHP. | • explains that [KHP] does not change due to absorption of water from the air [1 mark] |
23c) | KHP = 0.03 0.012 = 0.00036 moln×KHP = NaOHnn10.00036[NaOH] = = 0.0144 mol L0.025− | • provides suitable substitution [1 mark] • calculates [NaOH] [1 mark] |
QCAA sample response and marking criteria reproduced from the official guide.
Compare your working with the guide above.